There are various versions of Mint and Ubuntu that differ primarily depending on the default desktop. I would guess that the stock versions of both distros come with Libre Office installed, but if they don't, it is a simple matter of going into the package manager and checking the box in front of the Libre Office package and clicking "Apply," and Libre Office will install over your Internet connection. You might have to click "Update" first to refresh your packages list.
By the way, Mint is forked from Ubuntu (which is forked from Debian).
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